How Did We Get Here? The Tangled History of the Second Law of Thermodynamics
Stephen Wolfram
JANUARY 31, 2023
It began partly as an empirical law, and partly as something abstractly constructed on the basis of the idea of molecules, that nobody at the time knew for sure existed. And indeed particularly in chemistry and engineering it’s often been in the background, justifying all the computations routinely done using entropy.
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